## formation constant

https://doi.org/10.1351/goldbook.F02485
For a mononuclear binary complex, if a @C00930@ (central group) M (the 'metal') and a ligand L have been defined, then in the following expressions $$K_{n}$$ is the stepwise formation constant, and $$\beta_{n}$$ is the cumulative formation constant for the complex MLn. They can both be referred to as stability constants (stepwise and cumulative). $K_{n}=K(\text{ML}_{n- 1}+\text{L}\rightleftharpoons \text{ML}_{n})$ $\beta_{n} = K(\text{M}+n\text{L}\rightleftharpoons \text{ML}_{n})$
Source:
Orange Book, 2nd ed., p. 11 [Terms]