rearrangement ion

in mass spectrometry
https://doi.org/10.1351/goldbook.R05195
An electrically charged species, involving a molecular or parent ion, in which atoms or groups of atoms have transferred from one portion of a molecule or molecular moiety to another during the ionization fragmentation processes.
Sources:
Orange Book, 2nd ed., p. 205 (https://media.iupac.org/publications/analytical_compendium/)
PAC, 1991, 63, 1541. 'Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)' on page 1550 (https://doi.org/10.1351/pac199163101541)