Term: alternant https://doi.org/10.1351/goldbook.A00249 Definition: A conjugated system of π-electrons is termed alternant if its atoms can be divided into two sets so that no atom of one set is directly linked to any other atom of the same set. A00249-1.png A00249-2.png Related Terms: 1) conjugated system (http://doi.org/10.1351/goldbook.C01267). Images: 1) Not defined (https://goldbook.iupac.org/img/inline/A00249-1.png) 2) Not defined (https://goldbook.iupac.org/img/inline/A00249-2.png) Source: PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1082 (https://doi.org/10.1351/pac199466051077) Citation: 'alternant' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.A00249 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.