Term: arenium ions https://doi.org/10.1351/goldbook.A00436 Definition: Arenium σ-adducts (Wheland intermediates) (which are considered to be intermediates in electrophilic aromatic substitution reactions) and other cyclohexadienyl cations. A00436-1.png Related Terms: 1) cyclohexadienyl cations (http://doi.org/10.1351/goldbook.C01502). 2) adduct (http://doi.org/10.1351/goldbook.A00138). 3) hydron (http://doi.org/10.1351/goldbook.H02904). Image: nitrobenzenium ion (https://goldbook.iupac.org/img/inline/A00436-1.png) Source: Citation: 'arenium ions' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.A00436 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.