Term: charge separation https://doi.org/10.1351/goldbook.C00999 Definition: A process in which, under the influence of a suitable driving force (e.g. provided by photoexcitation), electronic charge moves in a direction that increases the difference in local charges between donor and acceptor sites. electron transfer between neutral species is one of the most important examples. Related Terms: 1) driving force (http://doi.org/10.1351/goldbook.D01860). 2) electron transfer (http://doi.org/10.1351/goldbook.E02011). 3) photoexcitation (http://doi.org/10.1351/goldbook.P04613). Source: PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2231 (https://doi.org/10.1351/pac199668122223) Citation: 'charge separation' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.C00999 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.