Term: critical pressure, \(p_{\text{c}}\) https://doi.org/10.1351/goldbook.C01397 Definition: The minimum pressure which would suffice to liquefy a substance at its critical temperature. Above the critical pressure, increasing the temperature will not cause a fluid to vaporize to give a two-phase system. Related Terms: 1) critical temperature (http://doi.org/10.1351/goldbook.C01402). Source: PAC, 1993, 65, 2397. 'Nomenclature for supercritical fluid chromatography and extraction (IUPAC Recommendations 1993)' on page 2399 (https://doi.org/10.1351/pac199365112397) Citation: 'critical pressure, \(p_{\text{c}}\)' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.C01397 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.