Term: diazonium salts https://doi.org/10.1351/goldbook.D01692 Definition: Compounds of structure RN2+Y−, in which R is generally but not necessarily aryl, and the cations of which are usually formulated as RN+≡N, E.g. PhN+≡N benzenediazonium chloride. They may also be named, from the canonical form RN=N+, hydrocarbyldiazenylium salts. Related Terms: 1) canonical form (http://doi.org/10.1351/goldbook.C01309). Source: PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1332 (https://doi.org/10.1351/pac199567081307) Citation: 'diazonium salts' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.D01692 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.