Term: dienes
https://doi.org/10.1351/goldbook.D01699

Definition:
Compounds that contain two fixed double bonds (usually assumed to be between carbon atoms). Dienes in which the two double-bond units are linked by one single bond are termed conjugated, e.g. CH2=CH–CH=CH2 buta-1,3-diene. Dienes in which the double bonds are adjacent are called cumulative, e.g. CH3–CH=C=CH2 buta-1,2-diene. Those in which one or more of the unsaturated carbon atoms is replaced by a heteroatom may be called heterodienes.

Related Terms:
1) alkenes (http://doi.org/10.1351/goldbook.A00224).
2) allenes (http://doi.org/10.1351/goldbook.A00238).
3) cumulenes (http://doi.org/10.1351/goldbook.C01440).
4) diols (http://doi.org/10.1351/goldbook.D01748).
5) olefins (http://doi.org/10.1351/goldbook.O04281).

Source: PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1332 (https://doi.org/10.1351/pac199567081307)

Citation: 'dienes' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.D01699

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