Term: disproportionation https://doi.org/10.1351/goldbook.D01799 Definition: Any chemical reaction of the type D01799-0.png, where A, A' and A'' are different chemical species. For example: D01799-1.png The reverse of disproportionation is called comproportionation. A special case of disproportionation (or 'dismutation') is 'radical disproportionation', exemplified by: D01799-2.png Reactions of the more general type: D01799-3.png are also loosely described as radical disproportionations. Related Terms: 1) comproportionation (http://doi.org/10.1351/goldbook.C01217). Images: 1) Not defined (https://goldbook.iupac.org/img/inline/D01799-0.png) 2) Not defined (https://goldbook.iupac.org/img/inline/D01799-1.png) 3) Not defined (https://goldbook.iupac.org/img/inline/D01799-2.png) 4) Not defined (https://goldbook.iupac.org/img/inline/D01799-3.png) Source: PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1107 (https://doi.org/10.1351/pac199466051077) Citation: 'disproportionation' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.D01799 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.