Term: effectively infinite thickness https://doi.org/10.1351/goldbook.E01895 Definition: Solid or liquid samples of one gram or more are generally used in X-ray spectroscopy. If the sample is thick enough so that the intensity of characteristic fluorescent radiation is not significantly modified by an increase in thickness, the sample is described as a bulk sample of effectively infinite thickness. Related Terms: 1) gram (http://doi.org/10.1351/goldbook.G02680). 2) x-ray spectroscopy (http://doi.org/10.1351/goldbook.X06718). 3) bulk sample (http://doi.org/10.1351/goldbook.B00756). Source: Orange Book, 2nd ed., p. 182 (https://media.iupac.org/publications/analytical_compendium/) Citation: 'effectively infinite thickness' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.E01895 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.