Term: electronegativity
https://doi.org/10.1351/goldbook.E01990

Definition:
Concept introduced by L. Pauling as the power of an atom to attract electrons to itself. There are several definitions of this quantity. According to Mulliken it is the average of the ionization energy and electron affinity of an atom, but more frequently a relative scale due to Pauling is used where dimensionless relative electronegativity differences are defined on the basis of bond dissociation energies, Ed, expressed in electronvolts: \[\chi _{\text{r}}\left(\text{A}\right)- \chi _{\text{r}}\left(\text{B}\right)=\left(\text{eV}\right)^{-\frac{1}{2}}\ \sqrt{E_{\text{d}}\left(\text{AB}\right)- \frac{1}{2}\ [E_{\text{d}}\left(\text{AA}\right)+E_{\text{d}}\left(\text{BB}\right)]}\] The scale is chosen so as to make the relative electronegativity of hydrogen χr = 2.1. The sign of the square root was chosen intuitively by Pauling.

Related Terms:
1) power (http://doi.org/10.1351/goldbook.P04792).
2) ionization energy (http://doi.org/10.1351/goldbook.I03199).
3) electron affinity (http://doi.org/10.1351/goldbook.E01977).
4) bond dissociation (http://doi.org/10.1351/goldbook.B00698).

Source: Green Book, 2nd ed., p. 20 (https://goldbook.iupac.org/files/pdf/green_book_2ed.pdf)

Citation: 'electronegativity' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.E01990

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