Term: entropy, \(S\) https://doi.org/10.1351/goldbook.E02149 Definition: Quantity the change in which is equal to the heat brought to the system in a reversible process at constant temperature divided by that temperature. Entropy is zero for an ideally ordered crystal at 0 K. In statistical thermodynamics \[S=k\ \ln W\] where k is the Boltzmann constant and W the number of possible arrangements of the system. Related Terms: 1) boltzmann constant (http://doi.org/10.1351/goldbook.B00695). Source: Green Book, 2nd ed., p. 48 (https://goldbook.iupac.org/files/pdf/green_book_2ed.pdf) Citation: 'entropy, \(S\)' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.E02149 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.