Term: Flory–Huggins theory https://doi.org/10.1351/goldbook.F02431 Definition: A thermodynamic theory of polymer solutions, first formulated independently by Flory and by Huggins, in which the thermodynamic quantities of the solution are derived from a simple concept of combinatorial entropy of mixing and a reduced Gibbs energy parameter, the 'χ parameter'. Related Terms: 1) entropy (http://doi.org/10.1351/goldbook.E02149). 2) χ parameter (http://doi.org/10.1351/goldbook.C00767). Source: Purple Book, 1st ed., p. 59 (http://old.iupac.org/publications/books/author/metanomski.html) Citation: 'Flory–Huggins theory' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.F02431 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.