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{"term":{"metadata":{"id":"02595","doi":"10.1351\/goldbook.G02595","code":"G02595","status":"current","longtitle":"IUPAC Gold Book - gauche effect","title":"gauche effect","contexts":[],"index":null,"version":null,"lastupdated":null},"definitions":{"definition":[{"id":"1","text":"The stabilization of the gauche (synclinal) conformation in a two carbon unit bonded vicinally to electronegative elements e.g. 1,2-difluoroethane.","contexts":{"in":[],"of":[]},"chemicals":[],"links":[{"type":"internal","url":"http:\/\/dev.goldbook.iupac.org\/terms\/view\/G02593"},{"type":"internal","url":"http:\/\/dev.goldbook.iupac.org\/terms\/view\/S06222"},{"type":"internal","url":"http:\/\/dev.goldbook.iupac.org\/terms\/view\/C01258"}],"math":[],"sources":[]},{"id":"2","text":"The destabilization of the gauche (synclinal) conformation in a two carbon unit bonded vicinally to large, soft and polarizable elements such as sulfur and bromine.","contexts":{"in":[],"of":[]},"chemicals":[],"links":[{"type":"internal","url":"http:\/\/dev.goldbook.iupac.org\/terms\/view\/G02593"},{"type":"internal","url":"http:\/\/dev.goldbook.iupac.org\/terms\/view\/S06222"},{"type":"internal","url":"http:\/\/dev.goldbook.iupac.org\/terms\/view\/C01258"}],"math":[],"sources":[]}]},"sources":null,"links":{"html":"http:\/\/dev.goldbook.iupac.org\/terms\/view\/G02595\/html","json":"http:\/\/dev.goldbook.iupac.org\/terms\/view\/G02595\/json","xml":"http:\/\/dev.goldbook.iupac.org\/terms\/view\/G02595\/xml","plain":"http:\/\/dev.goldbook.iupac.org\/terms\/view\/G02595\/plain","pdf":"http:\/\/dev.goldbook.iupac.org\/terms\/view\/G02595\/pdf","originalpdf":"http:\/\/iupac.org\/goldbook\/G02595.pdf"},"citeas":"IUPAC. Compendium of Chemical Terminology, 2nd ed. (the \"Gold Book\"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http:\/\/goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https:\/\/doi.org\/10.1351\/goldbook.","license":"Licensed under Creative Commons Attribution-NoDerivatives (CC-BY-ND) 4.0 International (https:\/\/creativecommons.org\/licenses\/by-nd\/4.0\/)","disclaimer":"The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.","accessed":"2021-10-23T03:59:58+00:00"}}