Term: Henry's law
https://doi.org/10.1351/goldbook.H02783

Definition:
The partial pressure (fugacity) of a solute (B) in a solution is directly proportional to the rational chemical activity (ax) of the solute; this relationship is called Henry's law: \[p_{\text{B}}=\frac{a_{x,\text{B}}}{\alpha _{x,\text{B}}^{\infty }}\] where a∞x,B is the rational solubility coefficient for infinite dilution, i.e. for pure solvent. For the solvent (A) the relationship is called Raoult's law, and the proportionality factor is the fugacity of the pure solvent, p(~)A∗: \[p_{\text{A}}=\overset{˜}{p}_{\text{A}}^{\ast }\ a_{\text{A}}\]

Related Terms:
1) partial pressure (http://doi.org/10.1351/goldbook.P04420).
2) henry (http://doi.org/10.1351/goldbook.H02782).
3) solubility (http://doi.org/10.1351/goldbook.S05740).
4) coefficient (http://doi.org/10.1351/goldbook.C01124).
5) raoult's law (http://doi.org/10.1351/goldbook.R05135).

Source: PAC, 1984, 56, 567. 'Physicochemical quantities and units in clinical chemistry with special emphasis on activities and activity coefficients (Recommendations 1983)' on page 571 (https://doi.org/10.1351/pac198456050567)

Citation: 'Henry's law' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.H02783

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