Term: highly oriented pyrolytic graphite (HOPG) https://doi.org/10.1351/goldbook.H02823 Definition: Highly oriented pyrolytic graphite (HOPG) is a pyrolytic graphite with an angular spread of the c-axes of the crystallites of less than 1 degree. Note: Commercial HOPG is usually produced by stress annealing at approximately 3300 K. Related Terms: 1) pyrolytic graphite (http://doi.org/10.1351/goldbook.P04964). Source: PAC, 1995, 67, 473. 'Recommended terminology for the description of carbon as a solid (IUPAC Recommendations 1995)' on page 495 (https://doi.org/10.1351/pac199567030473) Citation: 'highly oriented pyrolytic graphite (HOPG)' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.H02823 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.