Term: impact parameter, \(b\) https://doi.org/10.1351/goldbook.I02987 Definition: In simple hard sphere collision theory the distance of closest approach that would result for two particles in a collision if the particle trajectories were undeflected by the collision. Related Terms: 1) collision theory (http://doi.org/10.1351/goldbook.C01170). Source: Green Book, 2nd ed., p. 56 (https://goldbook.iupac.org/files/pdf/green_book_2ed.pdf) Citation: 'impact parameter, \(b\)' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.I02987 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.