Term: inertial defect https://doi.org/10.1351/goldbook.I03028 Definition: Difference of principal moments of inertia Δ = I C- I A- I B. For planar molecules it is close to zero and for non-planar molecules it is negative. Related Terms: 1) moments of inertia (http://doi.org/10.1351/goldbook.M04006). Source: Green Book, 2nd ed., p. 23 (https://goldbook.iupac.org/files/pdf/green_book_2ed.pdf) Citation: 'inertial defect' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.I03028 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.