Term: local fraction volatilized, χ v, \(\beta_{\text{v}}\) https://doi.org/10.1351/goldbook.L03606 Definition: The substance fraction of the volatilized component in the total desolvated component. The gaseous state includes free atoms, molecules and radicals. This quantity is measured in a defined part of the flame, usually the observation space. The fraction volatilized varies inversely with the size of the desolvated particles. Since χ v varies markedly with the height in the flame, its observed value represents an average. Related Terms: 1) substance fraction (http://doi.org/10.1351/goldbook.S06075). Source: Orange Book, 2nd ed., p. 168 (https://media.iupac.org/publications/analytical_compendium/) Citation: 'local fraction volatilized, χ v, \(\beta_{\text{v}}\)' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.L03606 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.