Term: microcanonical rate constant
https://doi.org/10.1351/goldbook.M03896

Definition:
A rate constant calculated by microcanonical variational transition-state theory and therefore a rate constant that relates to a fixed energy.

Related Terms:
1) rate constant (http://doi.org/10.1351/goldbook.O04322).
2) microcanonical variational transition-state theory (http://doi.org/10.1351/goldbook.M03897).

Source: PAC, 1996, 68, 149. 'A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)' on page 173 (https://doi.org/10.1351/pac199668010149)

Citation: 'microcanonical rate constant' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.M03896

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