Term: microscopic cross-section, \(\sigma\) https://doi.org/10.1351/goldbook.M03911 Definition: A measure of the probability of a specified interaction or reaction between an incident radiation and a target particle or system of particles. It is the reaction rate per target particle for a specified process divided by the flux of the incident radiation. In general, a specification is added of the type of radiation (e.g. neutron, photon), the energy of the incident radiation (e.g. thermal, epithermal, fast) and the type of interaction of reaction (e.g. activation, fission, scattering). Related Terms: 1) macroscopic cross-section (http://doi.org/10.1351/goldbook.M03674). 2) probability (http://doi.org/10.1351/goldbook.P04855). 3) neutron (<em>of a quantity</em>) (http://doi.org/10.1351/goldbook.N04116). 4) scattering (<em>of a quantity</em>) (<em>of a radiation</em>) (http://doi.org/10.1351/goldbook.S05487). 5) flux (<em>of a quantity</em>) (http://doi.org/10.1351/goldbook.F02461). 6) energy (<em>of a quantity</em>) (<em>of a radiation</em>) (http://doi.org/10.1351/goldbook.E02102). 7) activation (<em>of a quantity</em>) (<em>of a radiation</em>) (http://doi.org/10.1351/goldbook.A00103). 8) fission (<em>of a quantity</em>) (<em>of a radiation</em>) (http://doi.org/10.1351/goldbook.N04229). Source: Orange Book, 2nd ed., p. 217 (https://media.iupac.org/publications/analytical_compendium/) Citation: 'microscopic cross-section, \(\sigma\)' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.M03911 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.