Term: non-linear optical polymer
https://doi.org/10.1351/goldbook.NT07178

Definition:
Polymer that exhibits an optical effect brought about by electromagnetic radiation such that the magnitude of the effect is not proportional to the irradiance.

Notes:
0) An example of non-linear optical effects is the generation of higher harmonics of the incident light wave.
1) A polymer that exhibits a @N04197@ due to anisotropic electric susceptibilities when subjected to electric field together with light @I03255@ is called an electro-optical polymer. A polymer that exhibits electro-optical behavior combined with @P04591@ is called a photo-refractive polymer.

Related Terms:
1) non-linear optical effect (http://doi.org/10.1351/goldbook.N04197).
2) irradiation (http://doi.org/10.1351/goldbook.I03255).
3) photoconductivity (http://doi.org/10.1351/goldbook.P04591).

Source: PAC, 2004, 76, 889. 'Definitions of terms relating to reactions of polymers and to functional polymeric materials (IUPAC Recommendations 2003)' on page 900 (https://doi.org/10.1351/pac200476040889)

Citation: 'non-linear optical polymer' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.NT07178

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