Term: onium compounds https://doi.org/10.1351/goldbook.O04291 Definition: Cations (with their counter-ions) derived by addition of a hydron to a mononuclear parent hydride of the nitrogen, chalcogen and halogen families. (H4N+) ammonium (H3O+) oxonium (H2F+) fluoronium (H4P+) phosphonium (H3S+) sulfonium (H2Cl+) chloronium (H4As+) arsonium (H3Se+) selenonium (H2Br+) bromonium (H4Sb+) stibonium (H3Te+) telluronium (H2I+) iodonium (H4Bi+) bismuthonium Related Terms: 1) cations (http://doi.org/10.1351/goldbook.C00907). 2) hydron (<em>in an ion exchanger, in colloid chemistry</em>) (http://doi.org/10.1351/goldbook.H02904). 3) counter-ions (<em>in an ion exchanger, in colloid chemistry</em>) (http://doi.org/10.1351/goldbook.C01371). 4) parent hydride (<em>in an ion exchanger, in colloid chemistry</em>) (http://doi.org/10.1351/goldbook.P04405). Source: Citation: 'onium compounds' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.O04291 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.