Term: optical purity https://doi.org/10.1351/goldbook.O04310 Definition: The ratio of the observed optical rotation of a sample consisting of a mixture of enantiomers to the optical rotation of one pure enantiomer. Related Terms: 1) optical rotation (http://doi.org/10.1351/goldbook.O04312). 2) enantiomer (http://doi.org/10.1351/goldbook.E02069). 3) enantiomeric excess (http://doi.org/10.1351/goldbook.E02070). Source: PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2212 (https://doi.org/10.1351/pac199668122193) Citation: 'optical purity' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.O04310 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.