Term: organoheteryl groups https://doi.org/10.1351/goldbook.O04327 Definition: Univalent groups containing carbon, which are thus organic, but which have their free valence at an atom other than carbon. This collective term is seldom used; specific subclasses are more frequently encountered (organothio or organylthio, organogermanium or organylgermanium groups). The synonymous term organoelement groups is occasionally encountered. E.g. phenoxy, acetamido, pyridinio (C5H5N+), thiocyanato (N≡C–S−), trimethylsilyl; but not hydroxyphenyl, aminoacetyl. Related Terms: 1) valence (http://doi.org/10.1351/goldbook.V06588). 2) organyl (http://doi.org/10.1351/goldbook.O04329). Source: PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1353 (https://doi.org/10.1351/pac199567081307) Citation: 'organoheteryl groups' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.O04327 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.