Term: pre-exponential factor, A https://doi.org/10.1351/goldbook.P04811 Definition: coefficient in front of the exponential factor expressing the empirical temperature dependence of the rate coefficient, k, on temperature, T,k = A exp^(-Ea/R.T), where Ea is the activation energy. Related Terms: 1) coefficient (http://doi.org/10.1351/goldbook.C01124). 2) activation (http://doi.org/10.1351/goldbook.A00093). 3) rate coefficient (http://doi.org/10.1351/goldbook.R05137). Source: Green Book, 2nd ed., p. 56 (https://goldbook.iupac.org/files/pdf/green_book_2ed.pdf) Citation: 'pre-exponential factor, A' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.P04811 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.