Term: pressure gradient correction factor
https://doi.org/10.1351/goldbook.P04821

Definition:
A factor that corrects for the compressibility of the carrier gas. The values of the measured quantities obtained after multiplication by the factor j are independent of the pressure drop in the column. If p i, p o are respectively the pressures of the carrier gas at the inlet and outlet of the column, then j is given by: \[j=\frac{3\ [(\frac{p_{\text{i}}}{p_{\text{o}}})^{2}- 1]}{2\ [(\frac{p_{\text{i}}}{p_{\text{o}}})^{3}- 1]}\]

Related Terms:
1) carrier gas (http://doi.org/10.1351/goldbook.C00863).

Source: Orange Book, 2nd ed., p. 101 (https://media.iupac.org/publications/analytical_compendium/)

Citation: 'pressure gradient correction factor' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.P04821

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