Term: primary pH standards https://doi.org/10.1351/goldbook.P04837 Definition: Certain substances which meet the criteria of: reproducible preparation in a highly pure state; stability of solution over a reasonable period of time; having a low value of the residual liquid junction potential; having pH betwen 3 and 11. Related Terms: 1) liquid junction (http://doi.org/10.1351/goldbook.L03584). Source: Orange Book, 2nd ed., p. 19 (https://media.iupac.org/publications/analytical_compendium/) Citation: 'primary pH standards' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.P04837 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.