Term: pump-dump-probe technique https://doi.org/10.1351/goldbook.PT07465 Definition: Transient absorption spectroscopy using three pulses (a strong pump, a dump pulse that can alter the course of the reaction photoinduced by the first pulse, and a weak probe). In general, femtosecond laser pulses are used. Related Terms: 1) spectroscopy (http://doi.org/10.1351/goldbook.S05848). 2) laser (http://doi.org/10.1351/goldbook.L03459). Source: PAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 404 (https://doi.org/10.1351/pac200779030293) Citation: 'pump-dump-probe technique' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.PT07465 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.