Term: rate law (empirical differential rate equation) https://doi.org/10.1351/goldbook.R05141 Definition: An expression for the rate of reaction of a particular reaction in terms of concentrations of chemical species and constant parameters (normally rate coefficients and partial orders of reaction) only. For examples of rate laws see equations (1)-(3) under kinetic equivalence, and (1) under steady state. Related Terms: 1) rate of reaction (http://doi.org/10.1351/goldbook.R05156). 2) chemical species (http://doi.org/10.1351/goldbook.CT01038). 3) rate coefficients (http://doi.org/10.1351/goldbook.R05137). 4) orders of reaction (http://doi.org/10.1351/goldbook.O04322). 5) kinetic equivalence (http://doi.org/10.1351/goldbook.K03403). 6) steady state (http://doi.org/10.1351/goldbook.S05962). Source: PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1157 (https://doi.org/10.1351/pac199466051077) Citation: 'rate law (empirical differential rate equation)' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.R05141 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.