Term: steric factor
https://doi.org/10.1351/goldbook.S05998

Definition:
A factor introduced into simple versions of the collision theory of reactions to take care of the fact that the reaction probability depends on the certain mutual orientations of the reactant molecules.

Related Terms:
1) collision frequency (http://doi.org/10.1351/goldbook.C01166).
2) collision theory (http://doi.org/10.1351/goldbook.C01170).
3) reaction probability (http://doi.org/10.1351/goldbook.R05176).

Source: PAC, 1996, 68, 149. 'A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)' on page 187 (https://doi.org/10.1351/pac199668010149)

Citation: 'steric factor' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.S05998

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