Term: triple point https://doi.org/10.1351/goldbook.T06502 Definition: The point in a one-component system at which the temperature and pressure of three phases are in equilibrium. If there are p possible phases, there are p ! ( p- 3 ) ! 3 ! triple points. Example: In the sulfur system four possible triple points (one metastable) exist for the four phases comprising rhombic S (solid), monoclinic S (solid), S (liquid) and S (vapour). Related Terms: 1) metastable (http://doi.org/10.1351/goldbook.M03872). Source: PAC, 1994, 66, 577. 'Definitions of terms relating to phase transitions of the solid state (IUPAC Recommendations 1994)' on page 593 (https://doi.org/10.1351/pac199466030577) Citation: 'triple point' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.T06502 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.