Term: wavenumber, \(\sigma\), \(\tilde{\nu }\) https://doi.org/10.1351/goldbook.W06664 Definition: The reciprocal of the wavelength, λ, or the number of waves per unit length along the direction of propagation. The SI unit is m-1, but a commonly used unit is cm-1. Symbols ν ˜ in a vacuum, σ in a medium. Related Terms: 1) wavelength (http://doi.org/10.1351/goldbook.W06659). 2) propagation (http://doi.org/10.1351/goldbook.P04881). Source: Green Book, 2nd ed., p. 30 (https://goldbook.iupac.org/files/pdf/green_book_2ed.pdf) Citation: 'wavenumber, \(\sigma\), \(\tilde{\nu }\)' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.W06664 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.