In photoacoustic spectroscopy,
\(L = \sqrt{(D/\pi f)}\), where
\(D\) is
thermal diffusivity and
\(f\) is modulation frequency of the
electromagnetic radiation.
Notes: - SI unit: \(\pu{m}\). Common unit: \(\pu{\upmu\!m}\).
- \(\pu{63 \%}\) of the PAS signal originates within the thermal diffusion depth.
Source:
PAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 766 (https://doi.org/10.1515/pac-2019-0203)