umpolung

https://doi.org/10.1351/goldbook.U06551
Any process by which the normal alternating donor and acceptor reactivity pattern of a chain, which is due to the presence of O or N heteroatoms, is interchanged. Reactivity umpolung is most often achieved by temporary exchange of heteroatoms (N, O) by others, such as P, S and Se. The original meaning of the term has been extended to the reversal of any commonly accepted reactivity pattern. For example, reaction of R–C≡CX (X = halide) as a synthon for 'R–C≡C+ (i.e. @E02020@ acetylene) is an umpolung of the normal more common acetylide, R–C≡C (i.e. @N04249@) reactivity.
Source:
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1174 [Terms] [Paper]