https://doi.org/10.1351/goldbook.08374
Frequency shift in the nuclear magnetic resonance spectrum of a paramagnetic species that refers to the relative shift in NMR frequency for atoms in a metal (e.g., sodium) compared with the same atoms in a nonmetallic environment (e.g., as a salt).
Note:
The observed shift reflects the local magnetic field produced at the metal nucleus by the magnetization of the conduction electrons.
The observed shift reflects the local magnetic field produced at the metal nucleus by the magnetization of the conduction electrons.