https://doi.org/10.1351/goldbook.08422
Mechanism in nuclear magnetic resonance spectroscopy by which the component of the magnetization vector along the direction of the static magnetic induction reaches thermodynamic equilibrium with its surroundings through loss of energy of the excited nuclear spins to the surrounding molecular lattice. The resultant exponential decay of signal is characterized by the spin-lattice relaxation time (reciprocal of the rate constant of this mechanism).
Note:
dictates the time required between individual NMR scans to ensure the system has returned to equilibrium.