local molar polarizability

symbols: ν~, α^m, unit: J1C2m2mol1
synonym: molar polarizability
https://doi.org/10.1351/goldbook.08634
Defined under the assumption of the Lorentz local field by the Lorentz-Lorenz formula: α^m(ν~)=3Vmϵ0ϵ^(ν~)1ϵ^(ν~)+2=3Vmϵ0n^2(ν~)1n^2(ν~)+2 where Vm is the molar volume and ϵ^ and n^ are the complex dielectric constant and refractive index, respectively. To allow description of absorption, α^m(ν~) is complex: α^m(ν~)=αm(ν~)+iαm(ν~).
Notes:
  1. The imaginary molar polarizability shows the absorption band free from long range dielectric effects that distort the band shapes of very strong absorptions.
  2. SI unit: J1C2m2mol1.
Source:
PAC, 2021, 93, 647. (Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)) on page 753 [Terms] [Paper]