Nikolsky–Eisenman equation

https://doi.org/10.1351/goldbook.09120
Equation describing the contribution of interfering ions, i, to the electrode potential of an ion-selective electrode that is mainly dominated by the primary ion X. E=const+RTzXFln(aX+iKX,ipotai(zX/zi)) where E is the measured electrode potential of an ISE when the only variables are activities in the test solution. R is the gas constant, T the thermodynamic temperature, zX and zi are the numbers of electrons transferred by the analyte ion X and i, respectively, F is the Faraday constant, aX and ai the activity of X and i, respectively, and KX,ipot is the potentiometric selectivity coefficient for interfering ion i with respect to the primary ion X.
Note: The Nikolsky–Eisenman equation is an extension of the Nernst equation.
Source:
PAC, 2020, 92, 641. (Terminology of Electrochemical Methods of Analysis (IUPAC Recommendations 2019)) on page 666 [Terms] [Paper]