https://doi.org/10.1351/goldbook.09120
Equation describing the contribution of interfering ions, , to the electrode potential of an ion-selective electrode that is mainly dominated by the primary ion . where is the measured electrode potential of an ISE when the only variables are activities in the test solution. is the gas constant, the thermodynamic temperature, and are the numbers of electrons transferred by the analyte ion and , respectively, is the Faraday constant, and the activity of and , respectively, and is the potentiometric selectivity coefficient for interfering ion with respect to the primary ion .
Note: The Nikolsky–Eisenman equation is an extension of the Nernst equation.