https://doi.org/10.1351/goldbook.09354
Multi-electron process in which an atom is left in an excited state following a photoionization or Auger electron process, so that the outgoing electron has a characteristic kinetic energy slightly less than that of the parent photoelectron.
Note: Shakeup peaks are usually observed within of the parent peak. However, for gases where the background is low, shakeup peaks have been identified at kinetic energies up to less than that of the parent peak.
See also: shakeoff