chemically induced dynamic electron polarization (CIDEP)

https://doi.org/10.1351/goldbook.CT07339
Non-Boltzmann electron spin-state population produced in thermal or photochemical reactions, either from a combination of radical pairs (called radical-pair mechanism), or directly from the triplet state (called triplet mechanism) and detectable by ESR spectroscopy.
Source:
PAC, 2007, 79, 293. (Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)) on page 313 [Terms] [Paper]
Citation: 'chemically induced dynamic electron polarization' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.CT07339 RIS BibTex EndNote
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Last revised: February 24, 2014