https://doi.org/10.1351/goldbook.G02684
An allotropic form of the element carbon consisting of layers of hexagonally arranged carbon atoms in a planar condensed ring system graphene layers The layers are stacked parallel to each other in a three-dimensional crystalline long-range order. There are two allotropic forms with different stacking arrangements, hexagonal and rhombohedral. The chemical bonds within the layers are covalent with hybridization and with a C–C distance of . The weak bonds between the layers are metallic with a strength comparable to van der Waals bonding only.
Note: The term graphite is also used often but incorrectly to describe graphite materials, i.e. materials consisting of graphitic carbon made from carbon materials by processing to temperatures greater than , even though no perfect graphite structure is present.