interfacial layer width, σS

in thin films
https://doi.org/10.1351/goldbook.I03086
The characteristic length defined by the variance of the Gaussian function fitted to the gradient of the electron density profile established by X-ray specular reflectivity studies of the liquid interface.
Source:
PAC, 1994, 66, 1667. (Thin films including layers: terminology in relation to their preparation and characterization (IUPAC Recommendations 1994)) on page 1674 [Terms] [Paper]