https://doi.org/10.1351/goldbook.M03754
The heterogeneous diffusion rate constant defined for the case of the limiting current. A more general definition in terms of the electrode current densities is: or where is the electrode current density, is the stoichiometric number, is the charge number of the electrode reaction, is the Faraday constant, is the interfacial concentration, is the bulk concentration, is the transport number of species B, and is the charge number of species B.