photo-Claisen rearrangement

https://doi.org/10.1351/goldbook.PT07449
Rearrangement closely related to the photo-Fries rearrangement; it is experienced by aryl ethers (instead of aryl esters) and follows an analogous mechanism.
Note:
An example is the photoinduced rearrangement of phenyl ethers to ortho and para-alkyl phenols.
Source:
PAC, 2007, 79, 293. (Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)) on page 387 [Terms] [Paper]
Citation: 'photo-Claisen rearrangement' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.PT07449 RIS BibTex EndNote
Div. IIIPDFTextXMLJSON
Last revised: February 24, 2014