https://doi.org/10.1351/goldbook.R05121
A parameter characterizing the size of a particle of any shape. For a rigid particle consisting of mass elements of mass mi, each located at a distance ri from the centre of mass, the radius of gyration, s, is defined as the square root of the mass-average of ri2 for all the mass elements, i.e. s=imi ri2imi For a non-rigid particle, an average over all conformations is considered, i.e. <s2>=<imi ri2>imi The subscript zero is used to indicate unperturbed dimensions, as in <s2>01/2.
Source:
Purple Book, 1st ed., p. 48 [Terms] [Book]