rotational barrier

https://doi.org/10.1351/goldbook.R05408
In a rotation of groups about a bond, the potential energy barrier between two adjacent minima of the molecular entity as a function of the @T06406@.
Source:
PAC, 1996, 68, 2193. (Basic terminology of stereochemistry (IUPAC Recommendations 1996)) on page 2217 [Terms] [Paper]