https://doi.org/10.1351/goldbook.S05864
The unpaired electron density at a position of interest, usually at carbon, in a radical. It is often measured experimentally by electron paramagnetic resonance [EPR, ESR (electron spin resonance)] spectroscopy through hyperfine coupling constants of the atom or an attached hydrogen.
See also: radical centre
Source:
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1166 [Terms] [Paper]