temperature jump

A @R05285@ technique in which the temperature of a chemical system is suddenly raised. The system then relaxes to a new state of equilibrium, and analysis of the @R05285@ processes provides rate constants.
See also:
PAC, 1993, 65, 2291. (Nomenclature of kinetic methods of analysis (IUPAC Recommendations 1993)) on page 2297 [Terms] [Paper]
PAC, 1996, 68, 149. (A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)) on page 189 [Terms] [Paper]