https://doi.org/10.1351/goldbook.08214
Phenomenon whereby electrons can be delocalized from any of three (or more) groups to any other.
Example:
Notes:
- This may be contrasted with cross-conjugation.
- In Hammett-type correlations (linear Gibbs-energy relationships), this situation can lead to exalted substituent constants
or , as in solvolysis of or acidity of , respectively.